I've flown via 53 of these 100. Of the top 25, though, my only "miss" is #25.
I'll be surprised if my tally grows past 60 anytime in the next several years. Most of the airports I'm missing are outside of my travel needs-- I have no business there, no family there, or no desire to vacation there; or the airport is within 100 miles of a much larger airport with much better routings so I'll generally fly there & drive.