You can use your ROP miles to either get a TG award, or *A award.
An award using TG will only get you to MAD (
6314 miles, zone 4) for 105, 000 miles in Biz. You'd need then to buy a JK flight.
An award using *A, you could fly any *A airline BKK-TFN for 115,000 miles in C (
asia 1 to Europe / north africa). If you didn't have enough miles, you could purchase the needed miles (say 15,000 miles for USD 300).
You could thus fly TG/LH/LX/SQ per the results
here (picking 15 May nominally)
Hopefully that helps! TK