Originally Posted by
mantra
I am US Citizen and my wife is Indian nationality, US permanent resident.
You don't.
Your wife doesn't by virtue of her US residency which she should carry the requisite evidence of. This assumes she remains airside. Else she will need a visa. I have heard that this is not strictly enforced if you have a flight departing same day but from a different airport, eg arrive LHR, depart LGW. But this is annecdote.
I suggest you print out a copy of the rules from
www.ukvisas.gov.uk just in case the check-in staff aren't familiar with the rules.