Ouch. I feel your pain following a similar experience on NW ex-DTW recently. If the 50 euro voucher sounds generous now, wait until you encounter the various fare class restrictions. I don't suppose the 2000 FB miles are good for status?
I've had luck with KL reimbursing me for clearly documented and quantifiable damages resulting from delayed luggage, so perhaps your hotel night penalty will be reimbursed if you send a written claim.
I have no expertise on what additional compensation you could expect. My instinct is to ask for a variety of things that don't cost them much: more bonus miles, some free upgrades, etc.
Good luck.