For the best BBQ, you definintely have to take the road less traveled (literally).... some of the best BBQ I've ever had came from driving down some back road in TN, AR, or KY and stopping at some shack or gas station that said "BBQ here!"
I can't tell you exact locations, names of places (yes, it was THAT far out of the way).... but if you're willing to explore Americana, you'll be rewarded.