Atmos is a great program if you fly AS. I don’t know what earning rates look like when flying partners but that’s the most important part of the equation. You won’t be on AS metal much.
I have fun as a AA elite doing mileage runs on AS, as you can really get some great rates in premium cabins on long domestic flights; not sure if the inverse works as well.
AA is so strong out of DCA, I’d have a hard time making the jump. Especially in a geography where EP can be a game changer in the event of IRROPS.
If you want good domestic redemptions, do what I’ve done and put everything on a Chase or AmEx once you’ve qualified for OWE. Hard to beat DL redemptions using AF miles (though granted, DL is not strong in your area).
….and you’re missing out if not using AAhotels.