I have the opposite problem My profile state "smoking" room and I ALWAYS get stuck in a non-smoking room. I think I got a smoking room once, and it smelled worse than an ashtray.
No matter what I try, it's always non-smoking for me and I end up either smoking on the balcony (my preferred location) or changing rooms if there's no balcony.
Reserve the smoking room, you'll probably get a non-smoking one if you have anywhere near my luck

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Mary