Indeed it’s pretty poorly located, PPT-NOU and IPC-PPT were both about 6 hours IIRC (I did both in economy). Unless money is a major issue or a tiki tour is desired, only flying direct really makes sense
do AF or TN operate a premium economy cabin on this route?
eta: TN yes, on the 789, AF looks like mainly a 772 with W cabin. French bee looks bloody awful