Anyone with a First ticket gets free seat reservation, and an auto-seating if they don't go to MMB, so I guess there is more to that story (e.g. a very late booking? Unticketed?).
Otherwise refer him to the main EC261 thread, via the Dashboard, for the detailed calculation for downgrades. The dripping water should have been mentioned to the CSD / CSM since they can make instant amends via the iPad, and if that wasn't done the traveller should raise that as a separate issue with Customer Relations via the webform.
The card can of course be used in any ATM, supermarket or what not, you just lose a chunk on the exchange rate. It's important not to accept a card if there is no way to use it, and just as important to use it quickly in case the password slip is lost or is incorrectly matched to the card. The best thing to do is to take as much out as possible, then use the remainer of the card when next is a US dollar zone to exhaust the last few cents. Unfortunately the current cards don't appear to be touchless, otherwise they could be used on public transport (etc).