The overwhelming majority of the rooms face Ground Zero (which is to the West). There's an adjacent building to the East with ~zero clearance, so no guest rooms face the east directly. The eastern side of the building has elevator lobbies, stairwells and maid supply rooms rather than guest rooms.

I only saw the 53rd floor - 5302 is a Junior Suite that faces south (Statue of Liberty view) and west. I think 5301 was also a Junior Suite, with a South and East view (Statue and possibly Brooklyn/Manhattan Bridges). 5308 was a full suite that occupied the entire north end of the floor - I'd be surprised if even a Diamond would get this as an upgrade. Other than 5301 and 5308 all rooms had Ground Zero view.

These room numbers may not apply on lower floors - according to the floor plan on the back of the door, many of the rooms on 53 were suites that appeared to take up what would be 2 rooms on a lower floor.