Over many years (dating back to 1986 ....), have encountered lots of nationalities - mostly the 'usual' which have been referenced here already.
In the early days, there was a noticeably high percentage from Philippines, India and Britain & Ireland (similar pattern to Gulf Air really) ; but as we all know, this soon began to widen considerably in line with EK's aggressive expansion of both fleet & network.
My own standout rarities in recent times are :
Bonaire : believed to be the one & only Emirates 'representative' from the island
Austria : obviously not an unusual country per se, but apparently a rarity within EK
Zimbabwe : she was Purser on a BKK-SYD where I happened to be the only pax in F
All three were particularly charming, personable and were (IMHO) fine ambassadors for the airline. I still remember their names.
I also recall a very helpful (and amusing) CC member who was part Iranian and part British.