Some thoughts. None is particularly appetizing or comforting, but what the heck.
-- have you been watching the DCA-JFK flights to see if they typically land early?
-- have you considered DCA-LGA/JFK-SFO? (I know, Van Wyck traffic during rush hour is not idea. Just raising it).
-- Can you do WAS-NYC the night before to avoid the early am flight?
If nothing else, these other options should make the 6am flight more appealing!