100/8 = 12.67 hotel nights. I hope that's enough nights for you. If not, the Hyatt credit card may help to crank out a few more points.
As far as your core question - booking award nights for friends/family, the new Guest of Honor program will be of help to you. It will give all of the people you book Diamond privileges - club access, breakfast, late checkout, wifi. Link:
http://newsroom.hyatt.com/021215-Hya...yalty-Benefits
You shouldn't have a problem booking as many rooms as you desire as long as the hotel has availability. You might want to contact the hotel to confirm that it won't be an issue.
If your concern was whether or not Hyatt would frown on this, I think the answer is that they're encouraging Diamonds to gift award nights to friends/family through the Guest of Honor program.