If you've never been to Brussels, take the train to central station.
Helpful threads:
http://www.flyertalk.com/forum/europ...-brussels.html
http://www.flyertalk.com/forum/europ...-brussels.html
You don't need to go trough border control again when flying to VNO, just security. It is a long walk to the Schengen Concourse (A), don't be fooled by the shorter walk when arriving from EDI