I thought the National Palace Museum was phenomenal. It's too bad there isn't more display space. It can get very crowded with all of the tour buses. I enjoyed it without an English tour. They also have those recorded tour things available as well.
I liked the Baoan and Confucius temples. Go in the evening when it is more atmospheric.
I find the whole betel nut thing disgusting.
Make sure you try the curry beef noodle soup.
You really haven't got much time there. There is a very nice museum called the National History Museum at the botanic gardens that has a great collection of stuff. Old Chinese artifacts as well as more contemporary art.
http://en.wikipedia.org/wiki/National_Museum_of_History