The concept is relatively simple. If you want to have extra space while flying in Economy, then you can do so by paying an extra GBP99-GBP199 to have the seat next to you empty
I can see the most value in this if you are travelling alone and are in a 2-3-2 layout. You could get a window seat but have guaranteed access to the aisle and have more room to move about (without the risk of anyone stealing the extra space you've paid for).
More details on the Virgin Atlantic website or on my
www.flymeforfree.com