You can always ask them nicely first, my staff told me they often been told those seats all been located already.
So I guess the demand is quite high these days, even getting a paid bulkhead seat you really need to be there early. So the chance for a free one is slim.
BTW, I believe the bulkhead seats for the PE is easier to get, and they don't normally ask money for it - as long as you ask nicely

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