LHR-BOM
BOM-DEL (surface)
DEL-BKK
BKK-HKG (surface)
HKG-AKL
AKL-SCL
SCL-EZE (surface)
EZE-LIM
LIM-MEX
MEX-DFW
DFW-SJO
SJO-GUA (surface)
GUA-LAX
LAX-LHR
I rewrote your itinerary in another form, including the LAX/DFW swap mentioned above (although a direct GUA-LAX service seems to exist according to the OW interactive map):
LHR-BOM//DEL-BKK//HKG-AKL-SCL//EZE-LIM-MEX-DFW-SJO//GUA-
DFW-LHR
In this itinerary you'd have:
14 segments (including 4 surface segments) - you can have 2 more
1 flight segment in Asia, None in Southwest Pacific, 1 in South America, 3 in North America, None in Europe - you can add the 2 segments in any continent, since your contingent is still open in all continents
My suggestions for your two segments: DFW-
MAD-LHR (if you do not go back to LAX after GUA) and/or HKG-
SYD/MEL-AKL and/or EZE-
GRU-LIM and/or DFW-
MAD-
any other city in Europe served by both IB & BA-LHR - many other options open.
Enjoy your journey!