Originally Posted by LeisureFirst

No, it becomes available at T-3d when they allocate seats to non-status baby-holders. However, since a phone call is required to book it and many Golds/Silvers don't know about this, there is normally a good chance of nabbing it if you're quick of the mark at T-24. In this particular case, however, as BA Loyal pointed out (and I have checked) it seems to actually be occupied.